Ya.B. Zeldovich was a pre-eminent Soviet physicist whose seminal contributions spanned many fields ranging from physical chemistry to nuclear and particle physics, and finally astrophysics and cosmology. March 8, 2014 marks Zeldovich’s birth centenary, and this article attempts to convey the zest with which Zeldovich did science, and the important role he played in fostering and mentoring a whole generation of talented Scientists.

In the physics literature «ergodicity» is taken to mean that a system, including a macroscopic one, visits all microscopic states in a relatively short time. We show that this is an impossibility even if that time is billions of years. We also suggest that this feature does not contradict most physical considerations since those considerations deal with correlations of only a few particles.

n historical overview is given of the relevant steps that allowed the genesis of the quantum theory of the chemical bond, starting from the appearance of the new quantum mechanics and following later developments till approximately 1931. General ideas and some important details are discussed concerning molecular spectroscopy, as well as quantum computations for simple molecular systems performed within perturbative and variational approaches, for which the Born-Oppenheimer method provided a quantitative theory accounting for rotational, vibrational and electronic states. The novel concepts introduced by the Heitler-London theory, complemented by those underlying the method of the molecular orbitals, are critically analyzed along with some of their relevant applications.

We revise fundamental concepts in the dynamics of open quantum systems in the light of modern developments in the field. Our aim is to present a unified approach to the quantum evolution of open systems that incorporates the concepts and methods traditionally employed by different communities. We present in some detail the mathematical structure and the general properties of the dynamical maps underlying open system dynamics. We also discuss the microscopic derivation of dynamical equations, including both Markovian and non-Markovian evolutions.